The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+F+Cl / CFCl2CH2O2 / Lightfoot(1992)_298K_220-300nm(rec)

DATAFILE: CFCl2CH2O2_Lightfoot(1992)_298K_220-300nm(rec).txt
NAME: 2,2,2-fluorodichloroethylperoxy radical
FORMULA: CFCl2CH2O2
AUTHOR(YEAR): Lightfoot(1992)
T: 298K
λ: 220-300nm(rec)
BIBLIOGRAPHY: P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry", Atmos. Environ. 26A, 1805-1961 (1992); DOI: 10.1016/0960-1686(92)90423-I
COMMENTS: Recommendation based on a smooth fit to the data of

A.A. Jemi-Alade, P.D. Lightfoot, and R Lesclaux, "Measurements of the UV absorption cross-sections of CF3CCl2O2, CF3CHFO2, CFCl2CH2O2, and CF2ClCH2O2 in the gas phase," Chem. Phys. Lett. 179, 119-124 (1991, and

T.J. Wallington and O.J. Nielsen, "UV absorption spectra and kinetics of the self reaction of CFCl2CH2O2 and CF2ClCH2O2 radicals in the gas phase at 298 K," Int. J. Chem. Kinet. 23, 785-798 (1991)

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